Thermal maturity of Oligocene oil-source rocks in the Cuu Long basin Vietnam: An approach using the illitization of smectite
Abstract
The natural transformation of smectite-to-illite in Oligocene-Miocene sediments collected from an exploration well in Block 16-1, Cuu Long basin, has been examined in relation to quartz cementation and thermal maturity of source rocks. Evidences including X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM) data, identified that smectite is unstable with increasing burial temperature. Consequently, during the diagenesis stage, it was transformed to illite and released a significant amount of silica which formed micro-crystalline authigenic quartz within the clay matrix. The kinetic equation of the transformation of smectite to illite was utilized to evaluate the maximum paleotemperature for the first time; this indicated that the sediments had experienced a diagenesis episode in which the temperature was in a range of 100 - 140°C.
References
2. Burst Jr. et al. Post diagenesis clay mineral-environmental relationships in the Gulf Coast Eocene. Clay & Clay minerals. 1959; 6: p. 327 - 341.
3. Douglas N.M et al.. Clay & Clay minerals 6,327-341. Early clay diagenesis in Gulf Coast sediments: New insights from XRD profile modeling. Clays & Clayminerals. 2008; 56 (3): p. 359 - 379.
4. Fyhn M.B.W. et al. Geological development of the Central and South Vietnamese margin: Implications for the establishment of the Earst Sea. Indochinese escape tectonics and Cenozoic volcanism. Tectonophysics. Tecto-12686. 2009.
5. Gwang Lee et al. Geologic evolution of the Cuu Long and Nam Con Son Basins offshore Southern Vietnam. AAPG Bulletin1996; 85 (6): p. 1055 - 1082.
6. Hillier S. et al. Mlite/smectite diagenesis and its variable correlation with vitrinite reflection in the Pannonian Basin. Clays & Clayminerals. 1995; 43 (2): p. 174 - 183.
7. Hillier S. et al. Accurate quantitative of clay and other minerals in sandstones by XRD: Comparison ofa Rietveld and reference intensity ratio (RIR) method, and the importance of sample preparation. 2000.
8. Hower J. et al. Mechanism of burial metamorphism of argillaceous sediment: 1. Mineralogical and chemical evidence. Geological Society of America Bulletin. 1976; 87: р.725 - 737.
9. Huang et al. An experimentally derived kinetic model for smectite-to-illite conversation and its use as a geothermometer. Clays & Clayminerals. 1993; 41 (2):p. 162 - 177.
10. McKinley J.M. Clay mineral cements in sandstones. Special publication number 34 of the International Association Sedimentologists. 2003: p. 109 - 128.
11. Moore and Reynolds. X-ray diffraction and the identification and analysis of clayminerals. Oxford University Press, New York. 1997.
12. Richard M.P. et al.. Considerations and applications of the illite/smectite geothermometer in hydrocarbon- bearing rocks of Miocene to Mississippian age. Clays & Clayminerals. 1993 ; 41(2), p. 119 - 133.
13. Sorodon et al. Quantitative mineralogy of sedimentary rocks with emphasis on clay and with applications to K-Ar dating. Mineralogical Magazine2002; 66 (5): p.677 - 687.
14. Sorodon et al. interpretation of K-Ar dates of illitic clays from sedimentary rocks. 2002.
15. Susanne Gier et al. Diagenesis and reservoir quality of Miocene sandstone in the Vienna basin. Austria. Marine and Petroleum Geology. 2008: p.1 - 15.
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